Livia Baldini graduated in Architecture from Escola da Cidade in São Paulo, where she also worked as an assistant lecturer (2018–2019). She also studied at the Leicester School of Architecture and at IUAV University of Venice, where she obtained a master’s degree.

She has collaborated with a range of architectural practices in São Paulo, Paris, and Venice, including Shigeru Ban Architects, MU Architects, Studio21, Acayaba + Rosemberg, Renata Gaia Arquitetura, Terra Capobianco, and Movimento 90.

Since 2016, she has run her own architecture practice, focusing on architectural and exhibition projects. From 2021 onward, she has collaborated with several national pavilions at the Venice Biennale of Art and Architecture, including the Italian, Uruguayan, and Brazilian Pavilions.